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Chemical composition of wet and dry atmospheric depositions in an urban environment: Local, regional and long-range influences

TitleChemical composition of wet and dry atmospheric depositions in an urban environment: Local, regional and long-range influences
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2008
AuthorsMorselli, L., Bernardi E., Vassura I., Passarini F., and Tesini E.
JournalJournal of Atmospheric Chemistry
Volume59
Pagination151-170
ISSN01677764
KeywordsAmmonia, anthropogenic source, article, atmospheric deposition, Bologna [Emilia-Romagna], calcium ion, Chemical composition, chloride, concentration (composition), concentration response, Correlation analysis, dry deposition, Dust, Emilia-Romagna, Eurasia, Europe, factorial analysis, Italy, long range transport, magnesium ion, nitrate, Nitrogen, potassium ion, proton, sodium ion, Southern Europe, statistical analysis, sulfate, survey, urban area, urban atmosphere, wet deposition
Abstract

The results of a 8 year survey of wet and dry depositions collected in Bologna (Northern Italy) are presented and discussed: monthly fluxes of the main ions (hydrogen, sodium, potassium, calcium, magnesium, ammoniacal and nitrate nitrogen, sulphate and chloride) have been registered and statistically discussed. The trend of hydrogen ion, whose largest correlation in the global deposition was found with sulphate, is clearly downwards, with peaks mainly in winter months. By means of a data factor analysis, three main sources to explain the variability of the deposition chemistry were recognized: an anthropogenic contribution (particularly represented by NO3-, SO 42-, H+), the sea spray (Na+, Cl- and, to a lesser extent, K+ and Mg2+) and a terrigenous fraction, particularly characterized by higher Ca2+ concentration; however, some concentration peaks of this ion have been found in association with some episodes of Saharan dust transportation. © 2008 Springer Science+Business Media B.V.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-48449086826&doi=10.1007%2fs10874-008-9099-9&partnerID=40&md5=c8c9622119a02d91945a8ceaaaf95f55
DOI10.1007/s10874-008-9099-9
Citation KeyMorselli2008151