| Title | Enthalpies of vaporization of a homologous series of n-alkanes determined from vapor pressure measurements |
|---|---|
| Publication Type | Articolo su Rivista peer-reviewed |
| Year of Publication | 1994 |
| Authors | Piacente, Vincenzo, Fontana Danilo, and Scardala Paolo |
| Journal | Journal of Chemical and Engineering Data |
| Volume | 39 |
| Pagination | 231-237 |
| ISSN | 00219568 |
| Keywords | Angle measurement, Enthalpy, Least squares approximations, Molecular Weight, Paraffins, Pressure measurement, Temperature measurement, Thermal effects, Thermodynamic properties, Thermodynamic stability, Torsion angle measurement, Torsion-effusion method, Vapor pressure, Vaporization |
| Abstract | Vapor pressures and enthalpies of vaporization of the homologous series of n-alkanes CnH2n+2 (20 < n < 38 except n = 29 and 35) have been determined by the torsion-effusion method. Increments of about 2.7 kJ mol-1 of the ΔvapH°T for even- and odd-numbered n-alkanes and of about 5.3 kJ mol-1 of the ΔsubH°298.15 for the even-numbered n-alkanes due to the CH2 increment were found. |
| Notes | cited By 57 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0028418292&partnerID=40&md5=6e2e7f4dfa8bd93bb878d17e9e74b270 |
| Citation Key | Piacente1994231 |
