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A hydrometallurgical process for recovering rare earths and metals from spent fluorescent lamps

TitleA hydrometallurgical process for recovering rare earths and metals from spent fluorescent lamps
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2015
AuthorsDe Carolis, R., Fontana Danilo, Pietrantonio Massimiliana, Pucciarmati Stefano, and Torelli G.N.
JournalEnvironmental Engineering and Management Journal
Volume14
Pagination1603-1609
Date PublishedJUL
ISSN15829596
Keywordsfluorescent lamps, Hydrometallurgy, Rare earths, WEEE
Abstract

The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttrium and europium). Grinded powders were leached with several inorganic acids, then antimony and copper were recovered by electrodeposition; Y and Eu were finally precipitated as oxalates. The precipitate was dissolved and the rare earths were separated by solvent extraction. This approach, based on the holistic view of all elements contained in an End–of–Life complex product, ensures both environmental and economic sustainability since it allows waste reduction and materials recovery. © 2015, Gh. Asachi Technical University of Iasi. All rights reserved.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84939200243&partnerID=40&md5=026c60ac505d2cb844a486a720036627
Citation KeyDeCarolis20151603