| Title | Raman and NMR analysis of LiClO4 concentrated solutions in ethylene carbonate-propylene carbonate |
|---|---|
| Publication Type | Articolo su Rivista peer-reviewed |
| Year of Publication | 1996 |
| Authors | Cazzanelli, E., Mustarelli P., Benevelli F., Appetecchi Giovanni Battista, and Croce F. |
| Journal | Solid State Ionics |
| Volume | 86-88 |
| Pagination | 379-384 |
| ISSN | 01672738 |
| Keywords | Cation complexes, Concentrated solutions, Electrolytes, Ethylene carbonate, Gels, Lithium batteries, Lithium compounds, Lithium perchlorate, Nuclear magnetic resonance spectroscopy, Organic solvents, Propylene carbonate, Raman spectroscopy, Solutions |
| Abstract | A comparative Raman and 13C-NMR study has been performed on LiClO4 concentrated solutions in ethylene carbonate (EC)-propylene carbonate (PC), which are of interest for electrochemical devices like secondary lithium batteries. A phase transition has been detected near a ratio N = [Li+]/[EC + PC] ≅ 0.5. Below this threshold, Li+ ions are relatively free to move and are solvated by EC and PC with a coordination number, n, which approaches ∼2. In more concentrated solutions the cations seem to form a complex by "sandwiching" an EC and a PC molecule. |
| Notes | cited By 16 |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-18344404169&doi=10.1016%2f0167-2738%2896%2900154-3&partnerID=40&md5=fe65ac80358a3b2bb5a345e8286d3bdb |
| DOI | 10.1016/0167-2738(96)00154-3 |
| Citation Key | Cazzanelli1996379 |
