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Annealing protocols for pyrrolidinium bis(trifluoromethylsulfonyl)imide type ionic liquids

TitleAnnealing protocols for pyrrolidinium bis(trifluoromethylsulfonyl)imide type ionic liquids
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication2011
AuthorsFurlani, M., Albinsson I., Mellander B.-E., Appetecchi Giovanni Battista, and Passerini S.
JournalElectrochimica Acta
Volume57
Pagination220-227
ISSN00134686
KeywordsAnnealing, Bis(trifluoromethane sulfonyl)imide, Chemical engineering, Crystal packings, DSC, Electrochemistry, Ionic liquids, Pyrrolidinium, Specific protocol, Thermal behaviors, Thermal history
Abstract

The phase transitions in ionic liquids (ILs) of the N-alkyl-N- methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR 1ATFSI) family show a common pattern, which implies a typical and characteristic crystal packing. Many of these features are also observed for the N-alkyl- Nmethylpiperidinium bis(trifluoromethanesulfonyl)imide (PIP 1ATFSI) family. Here we report the thermal behavior of some ILs of the PYR 1ATFSI and PIP 1ATFSI families and a few others having different anions. The thermal history was found to decide which phases will appear and, therefore, specific protocols were defined to obtain the desired phases in a reasonable amount of time. © 2011 Elsevier Ltd. All rights reserved.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-82955205884&doi=10.1016%2fj.electacta.2011.08.056&partnerID=40&md5=3cb5ecdbd3dcd8a73121f3dbdaccf4df
DOI10.1016/j.electacta.2011.08.056
Citation KeyFurlani2011220